Synthesis of a new stable peristatic chiral pseudocryptand for simultaneous binding of boron and sodium


Togrul M., Topal G., YURDAKOÇ M., Hasgoren H.

JOURNAL OF HETEROCYCLIC CHEMISTRY, vol.42, no.6, pp.1201-1205, 2005 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 42 Issue: 6
  • Publication Date: 2005
  • Doi Number: 10.1002/jhet.5570420626
  • Journal Name: JOURNAL OF HETEROCYCLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1201-1205
  • Dokuz Eylül University Affiliated: Yes

Abstract

A new selective molecular receptor, borocryptate, based on the combination of the 15 membered ring diazatrioxa core and two saligenin units as binding sites for boron has been described. The resulting peristatic chiral compound is stable in air and easily converted to polynuclear complex, Na-borocryptate, without using an inert atmosphere.