Synthesis of a new stable peristatic chiral pseudocryptand for simultaneous binding of boron and sodium


Togrul M., Topal G., YURDAKOÇ M., Hasgoren H.

JOURNAL OF HETEROCYCLIC CHEMISTRY, cilt.42, sa.6, ss.1201-1205, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Sayı: 6
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1002/jhet.5570420626
  • Dergi Adı: JOURNAL OF HETEROCYCLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1201-1205
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

A new selective molecular receptor, borocryptate, based on the combination of the 15 membered ring diazatrioxa core and two saligenin units as binding sites for boron has been described. The resulting peristatic chiral compound is stable in air and easily converted to polynuclear complex, Na-borocryptate, without using an inert atmosphere.