1,2-HYDROGEN MIGRATION AND ALKENE FORMATION IN THE PHOTOEXCITED STATES OF ALKYLPHENYLDIAZOMETHANES

CELEBI, S; LEYVA, S; MODARELLI, DA; PLATZ, MS

doi:10.1021/ja00072a014

1,2-HYDROGEN MIGRATION AND ALKENE FORMATION IN THE PHOTOEXCITED STATES OF ALKYLPHENYLDIAZOMETHANES

Atıf İçin Kopyala

CELEBI S., LEYVA S., MODARELLI D., PLATZ M.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, cilt.115, sa.19, ss.8613-8620, 1993 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 115 Sayı: 19
Basım Tarihi: 1993
Doi Numarası: 10.1021/ja00072a014
Dergi Adı: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.8613-8620
Dokuz Eylül Üniversitesi Adresli: Hayır

Özet

Laser flash photolysis of alkylphenyldiazomethanes in the presence of pyridine produces easily detected ylides. The data indicate that photolysis of alkylphenyldiazomethanes leads to both carbene formation and direct formation of rearrangement products which do not derive from relaxed carbene intermediates.