Synthesis, characterization and catalytic activity in Suzuki-Miyaura coupling of palladacycle complexes with n-butyl-substituted N-heterocyclic carbene ligands
APPLIED ORGANOMETALLIC CHEMISTRY, cilt.32, sa.3, 2018 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 32 Sayı: 3
- Basım Tarihi: 2018
- Doi Numarası: 10.1002/aoc.4109
- Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Anahtar Kelimeler: N-heterocyclic carbene, palladacylic, Suzuki-Miyaura reaction, X-ray diffraction
- Dokuz Eylül Üniversitesi Adresli: Evet
Özet
A series of monomeric palladacycle complexes bearing n-butyl-substituted N-heterocyclic carbenes, namely [Pd(NHC)X(dmba)] (dmba: dimethylbenzylamine and [Pd(NHC)X(ppy)]; NHC: 1-n-butyl-3-substituted benzylimidazol-2-ylidene; ppy: 2-phenylpyridine), were prepared either by transmetallation from the corresponding silver carbene complexes or by the reaction of the corresponding acetate-bridged palladacycle dimer with N-heterocyclic carbene ligands in high yields. The palladium(II) complexes were characterized using elemental analyses, APCI-MS, H-1 NMR and C-13 NMR spectroscopies. These complexes are efficient in the Suzuki-Miyaura coupling reaction between phenylboronic acid and aryl bromides.