Experimental and theoretical study of the characteristics of lspr peaks for metal nps produced by controlling ar ambient gas pressure to enhance the efficiency of solar cells


Gezgin S. Y., Kepceoğlu A., KILIÇ H. Ş.

Canadian Journal of Physics, cilt.99, sa.10, ss.907-912, 2021 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 99 Sayı: 10
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1139/cjp-2020-0626
  • Dergi Adı: Canadian Journal of Physics
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, Chemical Abstracts Core, Communication Abstracts, Computer & Applied Sciences, Environment Index, Metadex, zbMATH, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.907-912
  • Anahtar Kelimeler: Ag, MNPBEM, Nanoparticle, Plasmonic, PLD, Solar cell, Thin film
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

In this study, silver (Ag) nanoparticle thin films were deposited on microscope slide glass and Si wafer substrates using the pulsed-laser deposition (PLD) technique in Ar ambient gas pressures of 1 x 103 and 7.5 x 101 mbar. AFM analysis has shown that the number of Ag nanoparticles reaching the substrate decreased with increasing Ar gas pressure. As a result of Ar ambient gas being allowed into the vacuum chamber, it was observed that the size and height of Ag nanoparticles decreased and the interparticle distances decreased. According to the absorption spectra taken by a UV–vis spectrom-eter, the wavelength where the localised surface plasmon resonance (LSPR) peak appeared was shifted towards the longer wavelength region in the solar spectrum as Ar background gas pressure was decreased. This experiment shows that LSPR wavelength can be tuned by adjusting the size of metal nanoparticles, which can be controlled by changing Ar gas pressure. The obtained extinction cross section spectra for Ag nanoparticle thin film was theoretically analysed and determined by using the metal nanoparticle–boundary element method (MNPBEM) toolbox simulation program. In this study, experimental spectrum and simulation data for metal nanoparticles were acquired, compared, and determined to be in agreement.