The stereoisomers of 1,3-dithiane 1,3-dioxides. Preparation, configuration and some conformational aspects

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Bien S., Celebi S. K., Kapon M.

Journal of the Chemical Society, Perkin Transactions 2, no.11, pp.1987-1990, 1990 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: Issue: 11
• Publication Date: 1990
• Doi Number: 10.1039/p29900001987
• Journal Name: Journal of the Chemical Society, Perkin Transactions 2
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.1987-1990
• Dokuz Eylül University Affiliated: No

Abstract

Oxidation of 1,3-dithiane with different oxidizing agents gave the 1,3-dithiane cis- and trans-1,3-dioxides 1 and 2. Their configuration and the conformational preferences of the sulphinyl oxygen atom have been determined by NMR spectroscopy and by X-ray analyses.