The stereoisomers of 1,3-dithiane 1,3-dioxides. Preparation, configuration and some conformational aspects

Bien, Shlomo; Celebi, Sol; Kapon, Moshe

doi:10.1039/p29900001987

The stereoisomers of 1,3-dithiane 1,3-dioxides. Preparation, configuration and some conformational aspects

Bien S., Celebi S. K., Kapon M.

Journal of the Chemical Society, Perkin Transactions 2, sa.11, ss.1987-1990, 1990 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: Sayı: 11
Basım Tarihi: 1990
Doi Numarası: 10.1039/p29900001987
Dergi Adı: Journal of the Chemical Society, Perkin Transactions 2
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1987-1990
Dokuz Eylül Üniversitesi Adresli: Hayır

Özet

Oxidation of 1,3-dithiane with different oxidizing agents gave the 1,3-dithiane cis- and trans-1,3-dioxides 1 and 2. Their configuration and the conformational preferences of the sulphinyl oxygen atom have been determined by NMR spectroscopy and by X-ray analyses.