Neutral cyclic sp(2)-sp(3)and sp(3)-sp(3)diboranes from N, N '-dicyclohexylcarbodiimide insertion into 1,2-dichlorodiboranes(4)

FIRINCI E., FIRINCI R., SEVİNÇEK R., AYGÜN M., ŞAHİN Y.

CHEMICAL COMMUNICATIONS, vol.56, no.68, pp.9807-9810, 2020 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 56 Issue: 68
  • Publication Date: 2020
  • Doi Number: 10.1039/d0cc03454a
  • Journal Name: CHEMICAL COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Communication Abstracts, EMBASE, MEDLINE, DIALNET
  • Page Numbers: pp.9807-9810
  • Dokuz Eylül University Affiliated: Yes

Abstract

We report the synthesis and structural characterization of new neutral cyclic sp(2)-sp(3)and sp(3)-sp(3)diboranes from the reaction ofN,N '-dicyclohexylcarbodiimide with 1,2-dichlorodiboranes(4) at room temperature. The present study is the first example of an insertion reaction of carbodiimide into diborane(4).