Neutral cyclic sp(2)-sp(3)and sp(3)-sp(3)diboranes from N, N '-dicyclohexylcarbodiimide insertion into 1,2-dichlorodiboranes(4)

FIRINCI, ERKAN; FIRINCI, RUKİYE; SEVİNÇEK, RESUL; AYGÜN, MUHİTTİN; ŞAHİN, YÜKSEL

doi:10.1039/d0cc03454a

Neutral cyclic sp(2)-sp(3)and sp(3)-sp(3)diboranes from N, N '-dicyclohexylcarbodiimide insertion into 1,2-dichlorodiboranes(4)

FIRINCI E., FIRINCI R., SEVİNÇEK R., AYGÜN M., ŞAHİN Y.

CHEMICAL COMMUNICATIONS, cilt.56, sa.68, ss.9807-9810, 2020 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 56 Sayı: 68
Basım Tarihi: 2020
Doi Numarası: 10.1039/d0cc03454a
Dergi Adı: CHEMICAL COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Communication Abstracts, EMBASE, MEDLINE, DIALNET
Sayfa Sayıları: ss.9807-9810
Dokuz Eylül Üniversitesi Adresli: Evet

Özet

We report the synthesis and structural characterization of new neutral cyclic sp(2)-sp(3)and sp(3)-sp(3)diboranes from the reaction ofN,N '-dicyclohexylcarbodiimide with 1,2-dichlorodiboranes(4) at room temperature. The present study is the first example of an insertion reaction of carbodiimide into diborane(4).