Synthesis and Characterization of New vic-Dioximes with Benzo-15-crown-5 Derivatives and Their Nickel(II), Copper(II), Cobalt(II) Complexes


Battaloglu R., Pekacar A. I., Yildiz Y. K.

ASIAN JOURNAL OF CHEMISTRY, vol.24, no.6, pp.2377-2379, 2012 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 24 Issue: 6
  • Publication Date: 2012
  • Journal Name: ASIAN JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2377-2379
  • Keywords: Macrocyclic ether, Cation binding, NMR spectroscopy, Glyoxime, Cation complexes, Solubility, PALLADIUM(II), URANYL(VI), PLATINUM(II)
  • Dokuz Eylül University Affiliated: Yes

Abstract

Benzo-15-crown-5-p-toluidino-glyoxime (1) and N(1-naphthy)amino-benzo-15-crown-5-glyoxime (2) were synthesized by classical methods. Their structures were confirmed by spectral techniques. Both of them were capable of forming complexes with various metal ions (Co2+, Cu2+ and Ni2+). The structure of the complexes was confirmed by FT-IR, mass spectra and elemental analyses.