Aromatic amine degradation in a UASB/CSTR sequential system treating Congo Red dye


Isik M., SPONZA D. T.

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, cilt.38, sa.10, ss.2301-2315, 2003 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 38 Sayı: 10
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1081/ese-120023387
  • Dergi Adı: JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2301-2315
  • Anahtar Kelimeler: anaerobic/aerobic system, aromatic amine, azo dye, Congo Red, ANAEROBIC-AEROBIC TREATMENT, SIMULATED TEXTILE EFFLUENT, WASTE-WATER, AZO DYES, METHANOGENIC CONDITIONS, UASB REACTOR, BIODEGRADATION, DECOLORIZATION, TOXICITY, SLUDGE
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

In this study an anaerobic (upflow anaerobic sludge blanket reactor)/aerobic (completely stirred tank reactor) sequential system was used to treat a synthetic wastewater with minerals and co-substrate together with 100-4000 mg L-1 of Congo Red dye (Direct red 28) (CR), which is a banned azo dye in Turkey. The effect of hydraulic retention time (HRT) on the decolorization and the COD removal efficiency was investigated at constant 100 mg L-1 Congo Red concentration. 77% of COD and 95% of color was removed at a HRT of 0.486 days and a maximum organic loading rate of 6.656 kg COD m(-3) day(-1) in the anaerobic/aerobic stage. In the continuous operations, 88% of COD, 99% of color and 91% of total aromatic amine (TAA) were removed at a HRT of 3.60 days and at a CR concentration of 4000 mg L-1. This corresponds to an organic loading rate of 1.81 kg COD m(-3) day(-1), and a CR dye loading rate of 46.37 g dye m(-3) h(-1), respectively, in the whole system. The TAA produced under anaerobic conditions was ultimately removed in the aerobic stage, resulting in very low aromatic amine recoveries (5-18%) in the last one. Therefore the aerobic effluents exhibited higher IC50 and specific methanogenic activities (SMA) compared to anaerobic and dye containing samples, indicating the reduced toxicity.