Mass transfer coefficients for polycyclic aromatic hydrocarbons (PAHs) to the water surface sampler: comparison to modeled results

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ODABAŞI M., Sofuoglu A., Holsen T.

ATMOSPHERIC ENVIRONMENT, cilt.35, sa.9, ss.1655-1662, 2001 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 35 Sayı: 9
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1016/s1352-2310(00)00439-8
  • Dergi Adı: ATMOSPHERIC ENVIRONMENT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1655-1662
  • Anahtar Kelimeler: PAHs, air-water exchange, water surface sampler, mass transfer coefficient, DRY DEPOSITION, ATMOSPHERIC DEPOSITION, POLYCHLORINATED-BIPHENYLS, ORGANIC-COMPOUNDS, CHESAPEAKE BAY, LAKE-SUPERIOR, AIR, EXCHANGE, INTERFACE, FLUXES
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

A sampling program was conducted between dune and October 1995 in Chicago, IL using a modified water surface sampler (WSS) and dry deposition plates to measure the particulate dry deposition and gas exchange of PAHs. Oxygen transfer experiments were also conducted to evaluate the collection properties of the WSS for gas-phase compounds. Gas-phase fluxes were determined by subtracting the dry deposition plate fluxes (particulate) from WSS fluxes (particulate + gas). These fluxes were divided by concurrently measured ambient concentrations to obtain overall gas phase mass transfer coefficients. Two different two-film models, one developed based on experiments performed with the WSS and, one previously published, were compared to these results. Experimentally determined average gas phase overall mass transfer coefficient (K-g) for seven PAHs was 0.74 +/- 0.52 cm s(-1). Experimental K-g values agreed well with those predicted by the model developed for WSS, The values predicted by previously proposed models were within a factor of 3 of the experimental ones. (C) 2001 Elsevier Science Ltd. All rights reserved.