Synthesis, structural and optical characterization of Nd: YAG powders via flame spray pyrolysis

Sakar N., Gergeroglu H., Akalın S. A., Oğuzlar S., Yıldırım S.

OPTICAL MATERIALS, cilt.103, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 103
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.optmat.2020.109819
  • Dergi Adı: OPTICAL MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Applied Science & Technology Source, Chimica, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC
  • Anahtar Kelimeler: Yttrium aluminum garnet (Y3Al5O12), Neodymium, Flame spray pyrolysis, Photoluminescence, Upconversion, NDYAG TRANSPARENT CERAMICS, SOL-GEL, COPRECIPITATION METHOD, FABRICATION, NANOPARTICLES, MICROSTRUCTURE, NANOPHOSPHORS, LUMINESCENCE, COMBUSTION, GROWTH
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

In this study, undoped Y3Al5O12 (YAG) and neodymium (Nd3+) doped (Nd: YAG) powders were synthesized by Flame Spray Pyrolysis (FSP) for the first time in literature. The synthesized powders were investigated about structural, morphological, elemental and optical properties by using Thermogravimetric - Differential Thermal Analysis (DTA-TG), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), X-ray Photoelectron Spectroscopy (XPS), Fourier Transformed Infrared Spectroscopy (FTIR), and photoluminescence spectroscopy (PL). The particle size range of undoped and Nd doped YAG powders produced by the FSP method was determined around 200-1100 nm. After calcination at 1000 degrees C, cubic YAG crystalline phases were successfully observed. The luminescence results as excitation, emission, and upconversion properties have been investigated for both undoped YAG (YG) and Nd3+ doped YAG with different dopant ratios as 1% (YG1), 3% (YG3) and %5 (YG5). When synthesized powders excited at 460 nm, the emission maxima observed at 540 nm and 808 nm. All YAG powders yielded bi-exponential decay curves. The highest decay time value was 1% Nd: YAG particle at 277 mu s. Furthermore, these powders