Syntheses and characterizations of copper(II)-supramolecular coordination compounds with 2,2-dimethylglutarate and diamine derivatives
JOURNAL OF MOLECULAR STRUCTURE, vol.1225, 2021 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 1225
- Publication Date: 2021
- Doi Number: 10.1016/j.molstruc.2020.129097
- Journal Name: JOURNAL OF MOLECULAR STRUCTURE
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, INSPEC
- Keywords: Copper(II) complexes, 2,2-dimethylglutaric acid, N,N-dimethylethylenediamine, N,N-diethylethylenediamine, N,N'-dimethyl-1,3-propanediamine
- Dokuz Eylül University Affiliated: Yes
Abstract
Three Copper(II) supramolecular coordination compounds (SCCs) named as {[Cu-2(mu-dmglu)2(mu-H2O)(dmen)(2)]center dot H2O}n (1), [Cu-2(mu-dmglu)(2)(deten)(2)]center dot 2H(2)O (2) and [Cu(mu-dmglu)(dmpen)](2) (3), have been synthesized using 2,2-dimethylglutaric acid (H(2)dmglu) and three different bidentate diamine ligands (dmen= N,N-dimethylethylenediamine, deten= N,N-diethylethylenediamine and dmpen= N,N'-dimethyl-1,3-propanediamine). The structures of SCCs were determined by single-crystal X-ray diffraction, FT-IR spectra, elemental, thermal analysis, powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). According to X-ray analysis, 1-3 crystallizes in the triclinic space group P-1. Although 2 and 3 have dinuclear structures, 1 displays 1D linear chain. In complex 1, adjacent 1D chains are extended to 3D supramolecular structure by hydrogen bonds. In complexes, 2 and 3, dinuclear units are broadened to 2D and 3D supramolecular structures with hydrogen bonding interactions. Moreover, the optical band gap energy of 1-3 have been measured with solid-state compounds. The results exhibited that the band gap energy varied from 3.45 eV to 3.39 eV. These compounds could be used like a semiconductor material. (C) 2020 Elsevier B.V. All rights reserved.