The synthesis, electrochemical properties and structural characterization of bis(N-(4-dimethylaminophenyl)-3,5-di-tert-butylsalicylaldiminato) copper(II)

Kilincarslan R., KARABIYIK H., Ulusoy M., Ayguen M., Cetinkaya B., Bueyuekguengoer O.

JOURNAL OF COORDINATION CHEMISTRY, vol.59, no.14, pp.1649-1656, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 59 Issue: 14
  • Publication Date: 2006
  • Doi Number: 10.1080/00958970500537952
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1649-1656
  • Keywords: Schiff base, salicylaldimine, copper(II) complex, crystal structure, electrochemistry, TETRADENTATE LIGANDS, CRYSTAL-STRUCTURES, NICKEL(II) COMPLEXES, MOLECULAR-STRUCTURE, BEHAVIOR, CU(II), NI(II)
  • Dokuz Eylül University Affiliated: Yes

Abstract

A Cu(II) complex of a Schiff base obtained by the condensation of N,N-dimethyl-1,4-phenylenediamine with 3,5-di-tert-butyl-2-hydroxybenzaldehyde has been synthesized and characterized. The structure of the complex was determined by single-crystal X-ray methods. The four-coordinate Cu(II) ion possesses a compressed tetrahedral coordination environment.