Preparation of compatible blends of poly(methyl methacrylate) used in dentistry with a reactive terpolymer containing maleic anhydride and their thermomechanical characterization

Boztug A., Coskun A., Bolayir G., Zengin H., Ozdemir A.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.100, sa.1, ss.363-367, 2006 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 100 Sayı: 1
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1002/app.23125
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.363-367
  • Anahtar Kelimeler: compatibility, blends, poly(methyl methacrylate) (PMMA), terpolymer, maleic anhydride, ALTERNATING COPOLYMERIZATION, MECHANICAL-PROPERTIES, ESTER DERIVATIVES, STYRENE, MORPHOLOGY, POLYAMIDE, BEHAVIOR, POLYMER
  • Dokuz Eylül Üniversitesi Adresli: Hayır

Özet

This study focuses on the preparation of compatible blends with the poly(methyl methacrylate) (PMMA) using a reactive terpolymer maleic anhydride-styrene-vinyl acetate (MA-St-VA). In the first series of experiments, binary blends of the PMMA and the MA-St-VA terpolymer have been prepared in tetrahydrofurane. The PMMA and the MA-St-VA terpolymer formed the compatible blends. The effects on thermomechanical properties of MA-St-VA terpolymer ratio in the blends were studied. The glass transition temperatures (T-g), thermal expansion coefficient (alpha), and other thermomechanical parameters for the blends have been established by TMA method and the compatibility of two polymers has been evaluated by these TMA parameters. The addition of MA-St-VA terpolymer to PMMA made a plasticizing effect on PMMA. This effect regularly changed with the increasing of the terpolymer in the blends. (c) 2006 Wiley Periodicals, Inc.