Development of Nanosized Mica Particles from Natural Mica by Sonication/Organic Intercalation Method for Pearlescent Pigment

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MALAYOĞLU U., Besun N.

MINERALS, cilt.10, sa.6, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 10 Sayı: 6
  • Basım Tarihi: 2020
  • Doi Numarası: 10.3390/min10060572
  • Dergi Adı: MINERALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, ABI/INFORM, Aerospace Database, Agricultural & Environmental Science Database, CAB Abstracts, Communication Abstracts, INSPEC, Metadex, Directory of Open Access Journals, Civil Engineering Abstracts
  • Anahtar Kelimeler: muscovite, mica, sonication, intercalation, nanomica, pearlescent pigment
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

In this study, the possibility of reducing natural mica particles to nanosizes without damaging its surface properties and smooth flake shape for pearlescent pigment application was investigated by using the sonication delamination method. For this purpose, the layer charge density of the natural mica mineral was reduced using surfactant intercalation followed by maximum exfoliation of mica interlayers with the help of sonication. Therefore, the delamination was achieved in a simple and more energy-efficient way by the sonication process and, in turn, the dimensions of mica were reduced to nanoscale with smooth surface features. With this new delamination process, the lowest particle thickness values were obtained as 0.061 microns after only 1 h sonication period. The results were found to be much significant when compared to the literature. Furthermore, the unique pearlescent pigment properties of mica particles were attributed to the characteristic shape and nanosized mica, which are coated with TiO2.