Asymmetric transfer hydrogenation reaction in water: Comparison of chiral proline amide/amine ruthenium(II) complexes
JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.779, ss.62-66, 2015 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 779
- Basım Tarihi: 2015
- Doi Numarası: 10.1016/j.jorganchem.2014.12.023
- Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.62-66
- Anahtar Kelimeler: L-proline, Ruthenium, Asymmetric transfer hydrogenation
- Dokuz Eylül Üniversitesi Adresli: Evet
Özet
Chiral proline amide/amine ligands (2, 3), synthesized by multi-step reaction starting from L-proline (1), were evaluated as catalyst generated in situ from [RuCl2(p-cymene)](2) for asymmetric transfer hydrogenation of aromatic ketones in the presence of sodium formiate and sodium dodecyl sulfate (SDS). The results revealed that efficiencies and enantioselectivities strongly depend on the N-substituents. (C) 2014 Elsevier B.V. All rights reserved.