Synthesis and structural characterization of (1,3-bis(methoxyethyl)-4,5-bis(2,4,6-trimethylphenyl)-imidazolidin-2-ylidene)chloro(1,5-cyclooctadiene)rhodium(I)

KARABIYIK, HASAN; Kilincarslan, R; Aygun, MUHİTTİN; Cetinkaya, B; Buyukgungor, O

doi:10.1080/00958970500344946

Synthesis and structural characterization of (1,3-bis(methoxyethyl)-4,5-bis(2,4,6-trimethylphenyl)-imidazolidin-2-ylidene)chloro(1,5-cyclooctadiene)rhodium(I)

KARABIYIK H., Kilincarslan R., Aygun M., Cetinkaya B., Buyukgungor O.

JOURNAL OF COORDINATION CHEMISTRY, cilt.59, sa.3, ss.343-350, 2006 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 59 Sayı: 3
Basım Tarihi: 2006
Doi Numarası: 10.1080/00958970500344946
Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.343-350
Anahtar Kelimeler: crystal structure, rhodium(I), N-heterocyclic carbine, cyclooctadiene
Dokuz Eylül Üniversitesi Adresli: Evet

Özet

A new N-heterocyclic carbene (NHC) ligand with bulky substituents and functionalized methoxy-donor side arms complexed with Rh(I) was synthesized and characterized by elemental analysis, H-1 and C-13 NMR, and IR spectroscopy. The crystal and molecular structure was determined by single-crystal X-ray diffraction techniques. Two carbon atoms in the cyclooctadiene ring and three ortho methyl groups have positional and orientational disorder, respectively. Rhodium has square-planar coordination geometry.