Electrical and mechanical properties of expanded graphite/high density polyethylene nanocomposites

SEVER K., Tavman I. H., SEKİ Y., TURGUT A., Omastova M., ÖZDEMİR İ.

COMPOSITES PART B-ENGINEERING, cilt.53, ss.226-233, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 53
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1016/j.compositesb.2013.04.069
  • Dergi Adı: COMPOSITES PART B-ENGINEERING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.226-233
  • Anahtar Kelimeler: Electrical properties, Mechanical properties, INTERCALATION POLYMERIZATION, CONDUCTING NANOCOMPOSITES, DIELECTRIC-PROPERTIES, POLYESTER COMPOSITES, PHYSICAL-PROPERTIES, THERMAL-PROPERTIES, ELASTIC PROPERTIES, BEHAVIOR, EXFOLIATION, MASTERBATCH
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

High density polyethylene (HDPE) were filled with expanded graphite particles that have different particle sizes, 5-7 mu m (EG5) and 40-55 mu m (EG50) in diameter. Nanocomposites were prepared by the melt-mixing technique using EG5 and EG50 at different weight ratios. Transmission Electron Microscopy (TEM) was used to observe the morphology of the nanocomposites. X-ray diffraction patterns of EG5-HDPE and EG50-HDPE nanocomposites were investigated. Tensile tests were carried out to determine tensile strength, Young's modulus and elongation at break values. The storage modulus and loss modulus were evaluated by Dynamic Mechanical Analysis (DMA). The effect of EG5 and EG50 on electrical conductivity of HDPE was also determined. The tensile strength of HDPE increased 18.7% and 8.5% when 40 wt% EG5 and EG50 was added into HDPE, respectively. The storage modulus of EG5-HDPE and EG50-HDPE is higher compared to that of HDPE. Incorporation of EG5 and EG10 into HDPE also increased the relaxation transition peak of HDPE. The values of electrical conductivity for EG50-HDPE nanocomposites under the same filler content obtained higher in comparison with those for EG5-HDPE nanocomposites. (C) 2013 Elsevier Ltd. All rights reserved.