Photochemical reactions of [M(CO)<sub>5</sub>THF] (M: Cr, Mo, and W) with tetradentate Schiff-bases

KARAHAN GÜLBAY S., KÖSE P., SUBAŞI E., TEMEL H.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.38, sa.7, ss.615-619, 2008 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 38 Sayı: 7
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1080/15533170802293303
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.615-619
  • Anahtar Kelimeler: N, N'-bis(2-hydroxynaphtalin-1-carbaldehydene)-1,2-bis(p-aminophenoxy)ethane, N, N'-bis(2-hydroxynaphtalin-1-carbaldehydene)-1,4-bis(p-aminophenoxy)butane, metal carbonyls, Schiff base
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

The new complexes, [(mu-CO)(2)Cr-2(4-H2L)(2)], 1; [(mu-CO)M-2(CO)(2)(eta(4)-H2L)(2)], [M = Mo; 2, W; 3]; [(mu-CO)(2)Cr-2(eta(4)-H2L')(2)], 4, and [(mu-CO)M-2(CO)(2)(eta(4)-H2L')(2)], [M = Mo; 5, W; 6] have been synthesized by the photochemical reactions of photogenerated intermediate, M(CO)(5)THF (M = Cr, Mo, W) with two oxygen and nitrogen donor Schiff base ligands, N,N'-bis(2-hydroxynaphtalin-1-carbaldehydene)-1,2-bis(p-aminophenoxy)ethane (H2L) and N,N'-bis(2-hydroxynaphtalin-1-carbalde-hydene)-1,4-bis(p-aminophenoxy)butane (H2L'). The complexes have been characterized by elemental analyses, LC-mass spectrometry, magnetic studies, FTIR, and H-1-NMR spectroscopy. The spectroscopic studies show that H2L and H2L' ligands are coordinated to the central metal as tetradentate ligands coordinating via their imine N and O donor atoms in (1-6).