Meta-bauxite deposit in the Tavsanli Zone, NW Turkey: A new locality for gem-quality diaspore formation


GÜNDOĞAN İ.

JOURNAL OF ASIAN EARTH SCIENCES-X, vol.8, 2022 (ESCI) identifier identifier

Abstract

The tectonic units of Sakarya Zone (Pontides) and Tavs,anli Zone (Anatolides) are exposed in the Mihaliccik area of central Anatolia. A Cretaceous accretionary complex that forms the Izmir-Ankara-Erzincan suture zone separates the units. Within this region, the Tavs,anli Zone is made up of a coherent series and tectonically overlying late Cretaceous me & PRIME;lange, which has undergone blueschist facies metamorphism. Coherent series consist of strongly retrogressed schists and conformably overlying platform-type thick marbles, known as the Ino & BULL;nu marbles. The Ino & BULL;nu marbles contain meta-bauxite lenses in the lower levels, which can be classified as karstic bauxites deposited in the karst holes within the original limestone. Considering the general stratigraphy of the Tavs,anli Zone, a middle Jurassic age can be envisaged for the bauxite formation. Geochemical data suggest that the bauxites were largely derived from redeposited argillic sediments, with minor and variable inputs from the weathering of intermediate to acidic rock. The mineral assemblage of the meta-bauxite consists of diaspore, chloritoid, muscovite, paragonite, Al-spinel (hercynite), magnetite, hematite and ilmenite. In addition, apatite, rutile, monazite, xenotime and zircon occur as accessory minerals. Limonite, goethite, akaganeite and kaolinite also formed during the latest stage of alteration. P-T conditions for the meta-bauxites are estimated as 20-27 kbar and 330-470 degrees C that are indicative of formation under high-P / low-T blueschist facies conditions. The meta-bauxites are cut by veins of diaspore, muscovite-paragonite, goethite, calcite and ankerite, and include gem-quality diaspore crystals up to 6 cm long. Textural evidence indicates that the diaspore formation is related to the extraction of aluminium from the meta-bauxite body and migration of Al-rich fluids into the shear zones during the last stage of the high-P metamorphism. During exhumation of the Tavs,anli Zone, these veins were brecciated by brittle deformation and the fractured minerals were cemented by granoblastic calcite and ankerite during the latest stage of the vein formation.