Simultaneous electrochemical determination of hydrazine and nitrite based on Au nanoparticles decorated on the poly(Nile Blue) modified carbon nanotube

Hatip M., Kocak S., Dursun Z.

ELECTROANALYSIS, vol.35, no.5, 2023 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 35 Issue: 5
  • Publication Date: 2023
  • Doi Number: 10.1002/elan.202200132
  • Journal Name: ELECTROANALYSIS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, BIOSIS, Chemical Abstracts Core, Chimica, Communication Abstracts, Metadex, Civil Engineering Abstracts
  • Keywords: gold nanoparticles, hydrazine and nitrite, poly(nile blue), simultaneous
  • Dokuz Eylül University Affiliated: Yes

Abstract

In this study, simultaneous determination of toxic hydrazine and nitrite was performed on composite electrodes of poly(Nile blue)(NB), carbon nanotube(CNT) and gold nanoparticles(AuNPs). The prepared AuNPs/CNT/poly(NB)/GCE was used for as a sensor platform for individual and simultaneous determination of hydrazine and nitrite. Electrodes were characterized by HRTEM, SEM, XPS, EIS. The LOD for nitrite and hydrazine was 5.0 mu M and 3.1 mu M at AuNP/CNT/poly(NB)/GCE, respectively. Also, sensitive amperometric determinations of hydrazine and nitrite were performed and LOD were calculated as 0.33 mu M and 0.68 mu M, respectively. The method was applied to sausage and river water samples and recovery results were obtained in the range 85-115 %.