Photochemical reactions of metal carbonyls [M(CO)(6) (M=Cr, Mo, W)] with N,N '-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

Subasi, ELİF; Temel, Hamdi; Senturk, Ozan; Ugur, Fadime

doi:10.1080/00958970600571703

Photochemical reactions of metal carbonyls [M(CO)(6) (M=Cr, Mo, W)] with N,N '-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

Subasi E., Temel H., Senturk O. S., Ugur F.

JOURNAL OF COORDINATION CHEMISTRY, cilt.59, sa.16, ss.1807-1811, 2006 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 59 Sayı: 16
Basım Tarihi: 2006
Doi Numarası: 10.1080/00958970600571703
Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1807-1811
Anahtar Kelimeler: N,N '-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane, metal carbonyls, Schiff base
Dokuz Eylül Üniversitesi Adresli: Evet

Özet

The complexes [M(CO)(4)(eta(2)-H2L)][M Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)(6)] [M Cr, Mo, W] with N, N'-bis(salicylidene)-1,2-bis-(o-aminophenoxy) ethane (H2L) in THF and characterized by elemental analyses, FTIR, (HNMR)-H-1 and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.