Utilization of montmorillonite nanocomposite incorporated with natural biopolymers and benzyl functionalized dicationic imidazolium based ionic liquid coated fiber for solid-phase microextraction of organochlorine pesticides prior to GC/MS and GC/ECD

Tagac A. A., Erdem P., Bozkurt S., MERDİVAN M.

ANALYTICA CHIMICA ACTA, cilt.1185, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1185
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.aca.2021.339075
  • Dergi Adı: ANALYTICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Food Science & Technology Abstracts, MEDLINE, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Clay, Biopolymers, Dicationic ionic liquid, Solid phase microextraction, Organochlorine pesticides, GC/MS and GC/ECD, POLYCYCLIC AROMATIC-HYDROCARBONS, EXTRACTION, CELLULOSE, SORBENT, CARBON, WATER, COMPOSITE
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

A novel montmorillonite clay (MMT) bionanocomposite modified with chitosan (CH), carboxymethyl cellulose (CMC), and benzylimidazolium based dicationic ionic liquid with tetraethylene glycol linker (DIL) was fabricated on stainless steel wire by in situ process. The MMT-CH-CMC-DIL coated solidphase microextraction (SPME) fiber was examined for the determination of organochlorine pesticides (OCPs) in real samples by HS-SPME-GC method using mass spectrometry (MS) and electron capture detector (ECD). Under optimized conditions, the proposed method exhibited low limits of detection (0.5 ng L-1 with MS and 0.1 ng L-1 with ECD detection), good linearities (R-2 = 0.9972-0.9993 with MS and 0.9987-0.9998 with ECD detection), favorable single-fiber repeatability, and fiber-to-fiber reproducibility (less than 8.2% and 9.9% for both types of detection) and high reusability around 125 cycles. Recovery studies were carried out for OCPs in tap water, green tea, and milk samples to verify the applicability of the developed SPME-GC method. (C) 2021 Elsevier B.V. All rights reserved.