Separation and preconcentration of La3+, Ce3+ and Y3+ using calix[4]resorcinarene impregnated on polymeric support

Gok C., Seyhan S., MERDİVAN M., YURDAKOÇ M.

MICROCHIMICA ACTA, cilt.157, ss.13-19, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 157
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1007/s00604-006-0646-2
  • Dergi Adı: MICROCHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.13-19
  • Anahtar Kelimeler: lanthanides, yttrium, preconcentration, resorcinarene, impregnation, Amberlite XAD-16, RARE-EARTH-ELEMENTS, THORIUM(IV), URANIUM(VI), LANTHANUM(III), SORPTION, RESINS
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

A procedure is proposed for separation and preconcentration of lanthanium, cerium and yttrium using octacarboxymethyl-C-methylcalix [4] resorcinarene impregnated onto a polymeric matrix, Amberlite XAD-16. The optimization process was carried out using 2 3 factorial design and three variables ( pH, concentration of metal ion, sorption flow rate) were regarded as factors. For Ce3+ extraction, the variance analysis revealed that pH and concentration of Ce3+ was statistically significant. However, for La3+ and Y3+ pH was significant only. The precision of the method (% RSD) was 2.27 for La3+, 1.97 for Ce3+ and 2.01 for Y3+ at 1 mu gmL(-1) for ten replicate analyses. The preconcentration factors of La3+, Ce3+ and Y3+ were 125, 83 and 100 respectively. The robustness of this procedure is demonstrated by the recovery achieved for determination of La3+, Ce3+ and Y3+ in the presence of several cations. The procedure was satisfactorily applied to the separation of La3+, Ce3+ and Y3+ from each other and also from common actinides such as UO22+ and Th4+ by sequential acidic elution system.