MODELING OF CARBON DIOXIDE FORMATION IN FLOWING ELECTROLYTE-DIRECT METHANOL FUEL CELLS

Ouellette D., Colpan C. Ö., Matida E., Cruickshank C. A.

9th International Conference on Fuel Cell Science, Engineering and Technology, Washington, Kiribati, 7 - 10 Ağustos 2011, ss.685-693 identifier

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Basıldığı Şehir: Washington
  • Basıldığı Ülke: Kiribati
  • Sayfa Sayıları: ss.685-693
  • Anahtar Kelimeler: DMFC, flowing electrolyte, mathematical modeling, carbon dioxide, two-phase, VISUALIZATION, PERFORMANCE, DMFC
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

A one-dimensional two-phase model has been developed for a direct methanol fuel cell (DMFC) and flowing electrolyte - direct methanol fuel cell (FE-DMFC). The model has been compared to experimental data found in literature and corresponds well. Using this model, the performance of the DMFC and FE-DMFC are evaluated and compared to one another as well as to their respective single phase models. It has been found that there is a substantial difference between a two-phase and single phase model. Furthermore, the FE-DMFC outperformed the DMFC when it came to methanol inlet concentrations and varying operating temperatures due to the FE-DMFC's ability to reduce the methanol crossover.