Nanostructured rutile TiO2 for selective photocatalytic oxidation of aromatic alcohols to aldehydes in water

YURDAKAL S., Palmisano G., Loddo V., Augugliaro V., Palmisano L.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, cilt.130, sa.5, ss.1568-1569, 2008 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 130 Sayı: 5
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1021/ja709989e
  • Dergi Adı: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Current Chemical Reactions (CCR)
  • Sayfa Sayıları: ss.1568-1569
  • Dokuz Eylül Üniversitesi Adresli: Hayır

Özet

Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).