Enamines of 1,3-dimethylbarbiturates and their symmetrical palladium(II) complexes: synthesis, characterization and biological activity

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Fırıncı R., Fırıncı E., Başbülbül G., Dabanca M. B., Barut Celepci D., Gunay M. E.

TRANSITION METAL CHEMISTRY, vol.44, no.4, pp.391-397, 2019 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 44 Issue: 4
  • Publication Date: 2019
  • Doi Number: 10.1007/s11243-019-00305-7
  • Journal Name: TRANSITION METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.391-397
  • Dokuz Eylül University Affiliated: Yes

Abstract

Three 1,3-dimethylbarbiturate-enamine derivatives and their symmetrical palladium(II) complexes were prepared and characterized by spectroscopic methods. In addition, the structures of the complexes were determined by single-crystal X-ray diffraction. The X-ray diffraction studies revealed the geometry around the Pd(II) atom in each complex is almost perfectly square-planar. Also, the ligands and their palladium(II) complexes were tested for antifungal and antibacterial activity against various clinical and food-borne microorganisms, revealing promising biological activities.