Akademik Veri Yönetim Sistemi
POLYMERS, cilt.17, sa.4, 2025 (SCI-Expanded, Scopus)
Nowadays, large amounts of wastewater arise from various industrial applications. The discharge of wastewater into the environment represents a threat to the aquatic ecosystem and human health. Thus, in the present study, innovative double-network (DN) hydrogels with pH-sensitive features and applicability as adsorbents in the treatment of leather dye wastewater were prepared. The polyelectrolyte, poly(N,N-dimethylaminoethyl methacrylate (PDMAEMA), was obtained via the radical polymerization process, while the supramolecular structure was co-assembled through physical interactions. As a novelty, the double network was obtained through the interpenetration of the supramolecular network in the cross-linked polymeric one. The new hydrogels were physico-chemically and morphologically characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and in terms of thermogravimetric analysis (TGA), swelling degree measurements, and dye adsorption studies. The DN hydrogels present interconnected macropores and high thermal stability. The swelling capacity of the dual network gels highlights a superadsorbent behavior at pH 3. Furthermore, the dye adsorption study highlights the effects of several variables (pH, concentration dose of adsorbent) on the ability of the gels to adsorb an anionic dye. The adsorption kinetics of the anionic dyes fitted the pseudo-first-order model (PFO). The estimated maximum adsorption capacities for the anionic dyes was 451 mg g-1 for PDMAEMA and 545 mg g-1 for DN gel.