Magnetic Behavior of Ternary Prussian Blue Analog in Presence Single-Ion Anisotropy


KIS ÇAM E., AYDINER E.

IEEE TRANSACTIONS ON MAGNETICS, vol.49, no.9, pp.4951-4955, 2013 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 49 Issue: 9
  • Publication Date: 2013
  • Doi Number: 10.1109/tmag.2013.2258932
  • Journal Name: IEEE TRANSACTIONS ON MAGNETICS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.4951-4955
  • Keywords: Compensation temperature, magnetic materials, magnetic recording, Monte Carlo methods
  • Dokuz Eylül University Affiliated: Yes

Abstract

In this work, with help of Monte Carlo simulation method, we have investigated the effects of single- ion anisotropy on magnetic properties of the Prussian blue analog ((FepMn1-pII)-Mn-II)(1.5)[Cr-III(CN)(6)]center dot nH(2)O consisting of three different Ising spins, S-A = 3/2, S-B = 2, and S-C = 5/2. We have found that the critical temperature T-c of this system nearly linear changes dependent upon the interaction ratio R for any mixing ratio p value, and the critical interaction R-c decreases for increasing D values. On the other hand, we have shown that the critical and compensation temperature of the model smoothly increase for increasing D values. In addition, we have demonstrated that the magnetic pole inversion can appear, and compensation temperature T-comp decreases for the increasing external magnetic field, dependent upon some values of the Hamiltonian parameters. As a result, we state that single- ion anisotropy can be used as a control parameter like mixing rate p to arrange the critical and compensation temperature of the Prussian blue analog ((FepMn1-pII)-Mn-II)(1.5)[Cr-III(CN)(6)]center dot nH(2)O.