BODIPY-vinyl dibromides as triplet sensitisers for photodynamic therapy and triplet-triplet annihilation upconversion

Dartar S., ÜÇÜNCÜ M., Karakus E., Hou Y., Zhao J., Emrullahoglu M.

CHEMICAL COMMUNICATIONS, cilt.57, sa.49, ss.6039-6042, 2021 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Sayı: 49
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1039/d1cc01881g
  • Dergi Adı: CHEMICAL COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, MEDLINE, DIALNET, Index Chemicus (IC)
  • Sayfa Sayıları: ss.6039-6042
  • Dokuz Eylül Üniversitesi Adresli: Hayır

Özet

We devised a new generation of halogen-based triplet sensitisers comprising geminal dibromides at the vinyl backbone of a BODIPY fluorophore. Incorporating geminal dibromides into the pi-conjugation of BODIPY enhanced intersystem crossing due to the heavy atom effect, which in turn improved the extent of excited triplet states.