Fate of return activated sludge after ozonation: an optimization study for sludge disintegration


Demir O., FİLİBELİ A.

ENVIRONMENTAL TECHNOLOGY, vol.33, no.16, pp.1869-1878, 2012 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 33 Issue: 16
  • Publication Date: 2012
  • Doi Number: 10.1080/09593330.2011.650220
  • Journal Name: ENVIRONMENTAL TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1869-1878
  • Keywords: sludge disintegration, solubilization, ozonation, cell lysis, sludge reduction, REDUCE EXCESS SLUDGE, WASTE-WATER, OZONE OXIDATION, SOLUBILIZATION, MINIMIZATION, FEASIBILITY, PERFORMANCE
  • Dokuz Eylül University Affiliated: Yes

Abstract

The effects of ozonation on sludge disintegration should be investigated before the application of ozone during biological treatment, in order to minimize excess sludge production. In this study, changes in sludge and supernatant after ozonation of return activated sludge were investigated for seven different ozone doses. The optimum ozone dose to avoid inhibition of ozonation and high ozone cost was determined in terms of disintegration degree as 0.05 g O-3/gTS. Suspended solid and volatile suspended solid concentrations of sludge decreased by 77.8% and 71.6%, respectively, at the optimum ozone dose. Ozonation significantly decomposed sludge flocs. The release of cell contents was proved by the increase of supernatant total nitrogen (TN) and phosphorus (TP). While TN increased from 7 mg/L to 151 mg/L, TP increased from 8.8 to 33 mg/L at the optimum ozone dose. The dewaterability and filterability characteristics of the ozonated sludge were also examined. Capillary suction time increased with increasing ozone dosage, but specific resistance to filtration increased to a specific value and then decreased dramatically. The particle size distribution changed significantly as a result of floc disruption at an optimum dose of 0.05 g O-3/gTS.