The Effect of Metal Salts on The Structures of 2,2-Dimethylglutarate Complexes with a Flexible 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene


KÖSE YAMAN P., ARICI M., ERER H., YEŞİLEL O. Z.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1229, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1229
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.molstruc.2020.129499
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, INSPEC
  • Anahtar Kelimeler: Coordination Polymers, 2,2-dimethylglutarate complexes, 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene complexes, 2,2-dimethylglutaric acid
  • Dokuz Eylül Üniversitesi Adresli: Evet

Özet

Five new coordination polymers, {[Co2(mu-dmg)(2)(mu-p-tmbix)(2)]center dot H2O}(n) (1), [ CO2(mu-dmg)(2)(mu-p-tmbix)(2)](n) (2), [Zn-2(mu-dmg)(2)(mu-P-tmbix)(2)](n) (3), [Cd(mu-dmg)(mu-p-tmbix)](n) (4) and [Cd(mu-dmg)(mu-p-tmbix)]center dot H2O}(n) (5) were successfully synthesized by using H(2)dmg and p-tmbix ligands under hydrothermal conditions (p-tmbix = 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene and H(2)dmg = 2,2-dimethylglutaric acid). Their structures were characterized by single crystal X-ray diffraction, elemental analyses, IR spectroscopy and powder X-ray diffraction (PXRD). Single crystal X-ray diffraction analysis revealed that compounds 1-4 displayed 3D frameworks and 2D network, respectively, while compound 5 exhibited two-fold interpenetrated 3D structure with 6(6)-dia topology. Furthermore, luminescence properties and thermal analyses (TG, DTA and DTA) of the compounds were investigated. (C) 2020 Elsevier B.V. All rights reserved.