Atıf İçin Kopyala
DENİZALTI S., Mercan D., Sen B., Gokce A. G., Cetinkaya B.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.779, ss.62-66, 2015 (SCI-Expanded)
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Yayın Türü:
Makale / Tam Makale
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Cilt numarası:
779
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Basım Tarihi:
2015
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Doi Numarası:
10.1016/j.jorganchem.2014.12.023
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Dergi Adı:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
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Derginin Tarandığı İndeksler:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
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Sayfa Sayıları:
ss.62-66
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Anahtar Kelimeler:
L-proline, Ruthenium, Asymmetric transfer hydrogenation, AROMATIC KETONES, ENANTIOSELECTIVE REDUCTION, PROCHIRAL KETONES, MICHAEL ADDITION, DIAMINE LIGANDS, ALDOL REACTION, ORGANOCATALYSTS, PHOSPHORAMIDES, ALLYLATION, ALDEHYDES
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Dokuz Eylül Üniversitesi Adresli:
Evet
Özet
Chiral proline amide/amine ligands (2, 3), synthesized by multi-step reaction starting from L-proline (1), were evaluated as catalyst generated in situ from [RuCl2(p-cymene)](2) for asymmetric transfer hydrogenation of aromatic ketones in the presence of sodium formiate and sodium dodecyl sulfate (SDS). The results revealed that efficiencies and enantioselectivities strongly depend on the N-substituents. (C) 2014 Elsevier B.V. All rights reserved.